Dataset of “Mastering palladium catalyzed cross-coupling reactions: the Critical role of in situ pre-catalyst reduction design”

Fantoni, Tommaso ; Palladino, Chiara ; Grigolato, Riccardo ; Muzzi, Beatrice ; Ferrazzano, Lucia ; Tolomelli, Alessandra ; Cabri, Walter (2025) Dataset of “Mastering palladium catalyzed cross-coupling reactions: the Critical role of in situ pre-catalyst reduction design”. University of Bologna. DOI 10.6092/unibo/amsacta/8177. [Dataset]
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Abstract

The dataset contains 31 P-NMR spectra as .fid files used to characterize palladium complexes formed during the in-situ generation of Pd(0) catalysts from Pd(II) precatalysts in cross-coupling reactions. The reduction process was examined via NMR to evaluate the influence of reagents, solvents, bases, ligands, and counterions. The spectra represent the optimal results obtained from the screening of each parameter.

Abstract
Document type
Dataset
Creators
CreatorsAffiliationORCID
Fantoni, TommasoTolomelli-Cabri Lab, Center for Chemical Catalysis, Department of Chemistry “Giacomo Ciamician”, University of Bologna, via Gobetti, 85-40129 Bologna, Ital0000-0002-9052-3432
Palladino, ChiaraTolomelli-Cabri Lab, Center for Chemical Catalysis, Department of Chemistry “Giacomo Ciamician”, University of Bologna, via Gobetti, 85-40129 Bologna, Ital0000-0001-8245-9584
Grigolato, RiccardoTolomelli-Cabri Lab, Center for Chemical Catalysis, Department of Chemistry “Giacomo Ciamician”, University of Bologna, via Gobetti, 85-40129 Bologna, Ital
Muzzi, BeatriceICCOM-CNR, Sesto Fiorentino FI, I-50019, Italy0000-0001-9151-7723
Ferrazzano, LuciaTolomelli-Cabri Lab, Center for Chemical Catalysis, Department of Chemistry “Giacomo Ciamician”, University of Bologna, via Gobetti, 85-40129 Bologna, Italy0000-0002-7083-2211
Tolomelli, AlessandraTolomelli-Cabri Lab, Center for Chemical Catalysis, Department of Chemistry “Giacomo Ciamician”, University of Bologna, via Gobetti, 85-40129 Bologna, Italy0000-0003-4202-1136
Cabri, WalterTolomelli-Cabri Lab, Center for Chemical Catalysis, Department of Chemistry “Giacomo Ciamician”, University of Bologna, via Gobetti, 85-40129 Bologna, Italy0000-0001-7865-0474
Keywords
cross-coupling, pre-catalyst reduction, NMR spectra
Subjects
Area 03 - Scienze chimiche > CHIM/06 Chimica organica
DOI
10.6092/unibo/amsacta/8177
Contributors
Name
Affiliation
ORCID
Type
Ferrazzano, Lucia
Tolomelli-Cabri Lab, Center for Chemical Catalysis, Department of Chemistry “Giacomo Ciamician”, University of Bologna, via Gobetti, 85-40129 Bologna, Italy
Contact person
Deposit date
11 Feb 2025 14:19
Last modified
11 Feb 2025 14:19
Related identifier
Related identifier type
Relation type
Code
DOI
this upload is supplement to
URI
https://amsacta.unibo.it/id/eprint/8177

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