Dataset of Synthesis, Structural Characterization and Reactivity of Macrocyclic Cyclo[2]malonates

Giuri, Demetra ; Ruffoli, Samuele (2026) Dataset of Synthesis, Structural Characterization and Reactivity of Macrocyclic Cyclo[2]malonates. University of Bologna. DOI 10.6092/unibo/amsacta/8989. [Dataset]
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Abstract

The dataset contains the NMR data as .fid files, the FT-IR as Origin files and HPLC-MS as .D files used to characterize a small library of cyclo[2]malonates. The optimization of reaction conditions enables selective access to dimeric macrocycles. While α-proton acidity is retained across the series, vanadyl (VO²⁺) binding is strongly governed by cavity size and conformational preorganization, suggesting a structure–function relationship.

Abstract
Tipologia del documento
Dataset
Autori
AutoreORCIDAffiliazioneROR
Giuri, Demetra0000-0001-5923-7836University of Bologna01111rn36
Ruffoli, SamueleUniversity of Bologna01111rn36
Parole chiave
macrocycles, NMR, HPLC-MS, FT-IR
Settori scientifico-disciplinari
Area 03 - Scienze chimiche > CHIM/06 Chimica organica
DOI
10.6092/unibo/amsacta/8989
Contributors
Contributor
ORCID
Tipo
Affiliazione
ROR
Vitale, Andrea
Data collector
University of Bologna
D'Addazio, Kevin
Data collector
University of Bologna
Pispero, Alessandro
Data collector
University of Bologna
Sartore, Daniele
Data collector
University of Bologna
Giuri, Demetra
Contact person
University of Bologna
Tomasini, Claudia
Project leader
University of Bologna
D'Agostino, Simone
Data curator
University of Bologna
Data di deposito
09 Giu 2026 09:16
Ultima modifica
09 Giu 2026 14:14
Risorse collegate
Tipologia
Relazione
Identificativo
DOI
questo contributo è un supplemento di
Nome del Progetto
CASTLE - Chirality and spin selectivity in electron transfer processes: from quantum detection to quantum enabled technologies
Programma di finanziamento
EC - HE
URI
https://amsacta.unibo.it/id/eprint/8989

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© ALMA MATER STUDIORUM - Università d Bologna, 2007-2026.

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