Giuri, Demetra ; Ruffoli, Samuele
(2026)
Dataset of Synthesis, Structural Characterization and Reactivity of Macrocyclic Cyclo[2]malonates.
University of Bologna.
DOI 10.6092/unibo/amsacta/8989.
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Abstract
The dataset contains the NMR data as .fid files, the FT-IR as Origin files and HPLC-MS as .D files used to characterize a small library of cyclo[2]malonates. The optimization of reaction conditions enables selective access to dimeric macrocycles. While α-proton acidity is retained across the series, vanadyl (VO²⁺) binding is strongly governed by cavity size and conformational preorganization, suggesting a structure–function relationship.
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